The first step in that direction (actually the second; the first step being the installation of the database itself) would be to create an EUL on the XE database.
I created a user named 'aa' using trusty SQL*Plus and gave it the privileges required by Discoverer (you can get a list of the privileges in the Discoverer doc guide - link to Discoverer Administrator doc on OTN).
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The first hurdle obviously was to see if Discoverer Administrator could even connect to XE (I couldn't think of any obvious reasons why it shouldn't).
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The connection was successful! The screen where Discoverer asks you to create an EUL is not here; I chose to create an EUL. Discoverer initiated the process of creating the EUL tables and views, and then populated them with default data.
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Once the EUL created successfully, the next step was to import the default Video Stores EUL. Actually, I didn't need to perform this step; I could have created a business area by hand, but this is simply convenient and quick.
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Previous related post: Oracle XE Database and Discoverer - 1 - Installing XE